Mikhail A. Vorotyntsev
Principal Publications

  1. Highly-Dispersed Palladium-Polypyrrole Nanocomposites Pd@PPy: "in-Water". Synthesis and Application for Catalytic Arylation of Heteroaromatics by Direct C-H Bond Activation, V. A. Zinovyeva, M. A. Vorotyntsev, I. Bezverkhyy, D. Chaumont, J.-C. Hierso, Adv. Funct. Mater., accepted in November 2010
  2. Electroactive Polymeric Material with Condensed Structure on the Basis of Magnesium(II) Polyporphine, M. A. Vorotyntsev, D. V. Konev, C. H. Devillers, I. Bezverkhyy, O. Heintz, Electrochim. Acta, accepted in October 2010, doi:10.1016/j.electacta.2010.10.039
  3. Mixed Solutions of Silver Cation and Chloride Anion in Acetonitrile: Voltammetric and EQCM Study, M. Skompska, M. A. Vorotyntsev, A. Rajchowska, O. V. Levin, Phys. Chem. Chem. Phys., 2010, vol. 12, 10525 - 10535
  4. Magnesium(II) Polyporphine: The First Electron-Conducting Polymer with Directly Linked Unsubstituted Porphyrin Units Obtained by Electrooxidation at a Very Low Potential, M. A. Vorotyntsev, D. V. Konev, C. H. Devillers, I. Bezverkhyy, O. Heintz, Electrochim. Acta, 2010, vol. 55, 6703-6714
  5. Diffusional Transport in Ionic Liquids: Stokes-Einstein Relation or "Sliding Sphere" Model? Ferrocene (Fc) in Imidazolium Liquids, M. A. Vorotyntsev, V. A. Zinovyeva, M. Picquet, Electrochim. Acta, 2010, vol. 55, 5063-5070
  6. Electropolymerization of Pyrrole in Acetonitrile as Affected by the Nature of Substitute and Deposition Potential, M. Graczyk-Zajac, S. Yu. Vassiliev, M. A. Vorotyntsev, G. A. Tsirlina, J. Solid State Electrochem., 2010, vol. 14, 2039-2048
  7. Mechanisms of Electropolymerization and Redox Activity: Fundamental Aspects, M. A. Vorotyntsev, V. A. Zinovyeva, D. V. Konev, In: Electropolymerization: Concepts, Materials and Applications, S. Cosnier and A. A. Karyakin, Eds., Wiley-VCH, Weinheim, chapter 2, 2010, pp. 27-50
  8. Electrochemical and Spectral Properties of Ferrocene (Fc) in Ionic Liquid: 1-Butyl-3-Methylimidazolium Triflimide, [BMIM][NTf2]. Concentration Effects, M. A. Vorotyntsev, V. A. Zinovyeva, D. V. Konev, M. Picquet, L. Gaillon, C. Rizzi, J. Phys. Chem. B, 2009, vol. 113, 1085-1099
  9. Synthesis and Characterization of Palladium Nanoparticle/Polypyrrole Composites, S. V. Vasilyeva, M. A. Vorotyntsev, I. Bezverkhyy, R. Chassagnon, O. Heintz, E. Lesniewska, J. Phys. Chem. C, 2008, vol. 112, 19878-19885
  10. Electrochemistry of Electroactive Materials, A. R. Hillman, P. J. Kulesza, M. A. Vorotyntsev, Electrochim. Acta, 2008, vol. 53, 3742-3743
  11. Electrochemical Properties of Metallocene Hydroxo and Oxo Complexes of Ta(V): [Cp*(CpR)TaOHCl]+ and Cp*(CpR)TaOCl, with R = H, SiMe3 or (CH2)3NC4H4 . Electrochemical Deposition of Conducting Polymer Film with Incorporated Tantalocene Complexes, M. Skompska, M. A. Vorotyntsev, J. Goux, P. Le Gendre, C. Moise, Electrochim. Acta, 2008, vol. 53, 3843-3852
  12. Metallocene-Containing Conjugated Polymers, M. A. Vorotyntsev, S. V. Vasilyeva, Adv. Colloid Interface Sci., 2008, vol. 139, 99-151
  13. Electrochemical and Spectral properties of Some Tantalocene Derivatives with One Pentamethylated Cyclopentadienyl Ligand: Cp*(Cp-R)TaCl2 , R = H, SiMe3 or (CH2)3NC4H4, M. A. Vorotyntsev, M. Skompska, M. Graczyk, J. Heinze, J. Goux, P. Le Gendre, C. Moise, J. Solid State Electrochemistry, 2008, vol. 12, 421-435
  14. Polypyrrole Films Functionalized with Pendant Titanocene Dichloride Complexes: Ellipsometric Study of the Electropolymerization Process, J. Correia, M. Graczyk, L. M. Abrantes, M. A. Vorotyntsev, Electrochim. Acta, 2007, vol. 53, 1195-1205
  15. Effect of Interparticle Interactions on the Rate of Injection of Charge Carriers into Electroactive Polymer Films, V. V. Malev, O. V. Levin, M. A. Vorotyntsev, Russ. J. Electrochem., 2007, vol. 43, 1016-1025
  16. Electrochemistry of Electroactive Materials, M. A. Vorotyntsev , F. Scholz, J. Solid State Electrochemistry, 2006, vol. 11, 1007-1007
  17. Model Treatment of Double Layer Charging in Electroactive Polymer Films with Two Kinds of Charge Carriers, V. V. Malev, O. V. Levin, M. A. Vorotyntsev, Electrochim. Acta, 2006, vol. 52, 133-151
  18. Electrochemically Reduced Titanocene Dichloride as a Catalyst of Reductive Dehalogenation of Organic Halides, T. V. Magdesieva, M. Graczyk, A. Vallat, O. M. Nikitin, P. I. Demyanova, K. P. Butin, M. A. Vorotyntsev, Electrochim. Acta, 2006, vol. 52, 1265-1280.
  19. Electrosynthesis and Properties of Poly(3,4-ethylenedioxythiophene) Films Functionalized with Titanocene Dichloride Complex, M. Skompska, M. A. Vorotyntsev, M. Refczynska, J. Goux, E. Lesniewska, G. Boni, C. Moise, Electrochim. Acta, 2006, vol. 51, 2108-2119.
  20. Reductive Electrocatalytic Dehalogenation of Nitrobenzyl Halogenides: Nitrophylic or Halophylic Attack, T. V. Magdesieva, O. M. Nikitin, P. I. Demyanova, M. Graczyk, A. Vallat, M. A. Vorotyntsev, K. P. Butin, Russ. Chem. Bull., 2005, vol. 54, 201-210.
  21. Application of Novel Refinement Method for Accurate Determination of Chemical Diffusion Coefficients in Electroactive Materials by Potential Step Techniques, M. D. Levi, R. Demadrille, A. Pron, M. A. Vorotyntsev, Y. Gofer, D. Aurbach, J. Electrochem. Soc., 2005, vol. 152, E61-E67.
  22. Electrochemistry of Electroactive Materials, J. Heinze; M. A. Vorotyntsev, Electrochim. Acta, 2005, vol. 50, 1449.
  23. Mechanism of Redox Transformation of Titanocene Dichloride Centers Immobilized inside a Polypyrrole Matrix - EQCM and XPS Evidences, M. Skompska, M. A. Vorotyntsev, J. Goux, C. Moise, O. Heintz, Y. S. Cohen, M. D. Levi, Y. Gofer, G. Salitra, D. Aurbach, Electrochim. Acta, 2005, vol. 50, 1635-1641
  24. The Role of Electrochemistry in the Sustained Development of Modern Societies, C. Brett, C. Cominellis, E. R. Gonzalez, O. Hammerich, P. Marcus, A. Tadjeddine, M. A. Vorotyntsev, Electrochim. Acta, 2004, vol. 49, n° 22-23.
  25. Reactions of Solute Species at an Electrode Modified with Titanocene Functionalized Polypyrrole Film: Ferrocene and Titanocene Dichloride, M. A. Vorotyntsev, M. Graczyk, A. Lisowska-Oleksiak, J. Goux, C. Moise, J. Solid State Electrochem., 2004, vol. 8, 818-827
  26. Spectroelectrochemistry of Conducting Polymers, B. M. Grafov; A. V. Vannikov; M. A. Vorotyntsev, Russ. J. Electrochem., 2004, vol. 40, 227-228.
  27. Spatially Limited Diffusion Coupled with Ohmic Potential Drop and/or Slow Interfacial Exchange: A New Method to Determine the Diffusion Time Constant and External Resistance from Potential Step (PITT) Experiments, M. A. Vorotyntsev, M. D. Levi, D. Aurbach, J. Electroanal. Chem., 2004, vol. 572, 299-307
  28. Influence of Chloride Anion on Electrodeposition and Electroactivity of the Polymer Matrix in Polypyrrole, Poly(N-methylpyrrole) and Polypyrrole Derivative Functionalized by Titanocene Centers, in Dry Non-Aqueous Solutions, M. Skompska, M. A. Vorotyntsev, J. Solid State Electrochem., 2004, vol. 8, 360-368
  29. Memory Effects in Functionalized Conducting Polymer Films: Titanocene Derivatized Polypyrrole in Contact with THF Solutions, M. A. Vorotyntsev, M. Skompska, E. Pousson, J. Goux, C. Moise, J. Electroanal. Chem., 2003, vol. 552C, 307-317.
  30. Studies of the Reduction of (C5Me5)2Mo2O5 in Methanol - Water - Acetate Solutions by On-Line Electrochemical Flow Cell and Electrospray Mass Spectrometry, J. Gun, A. D. Modestov, O. Lev, D. Saurenz, M. A. Vorotyntsev, R. Poli, Eur. J. Inorg. Chem., 2003, 482-492.
  31. Charging Process in Percolating Systems, M. A. Vorotyntsev, K. Aoki, J. Heinze, Russ. J. Electrochem., 2003, vol. 39, 182-191.(Elektrokhimiya, 2003, vol. 39, 203-213.)
  32. Interpretation of PITT Experiments for Various Li-intercalation Electrodes, M. D. Levi, D. Aurbach, M. A. Vorotyntsev, Condensed Matter Physics, 2002, vol. 5, 1-34.
  33. Impedance of Thin Films with Two Mobile Charge Carriers. Interfacial Exchange of Both Species with Adjacent Media. Effect of Double Layer Charging, M. A. Vorotyntsev, Electrochimica Acta, 2002, vol. 47, 2071-2079.
  34. Electrochemical Double Layers, A. A. Kornyshev, E. Spohr, M. A. Vorotyntsev, In: Encyclopedia of Electrochemistry, vol. 1: Thermodynamics and Electrified Interfaces / E. Gileadi, M. I. Urbakh, Eds., Wiley-VCH, New York, 2002, chapter 2.1, pp. 33-132.
  35. Redox Properties of Titanocene-Pyrrole Derivative and Its Electropolymerization, M. A. Vorotyntsev, M. Casalta, E. Pousson, L. Roullier, G. Boni, C. Moise, Electrochimica Acta, 2001, vol. 46, 4017-4033.
  36. Electrochemistry of Electroactive Polymer Films, P. J. Kulesza, M. A. Vorotyntsev, Electrochimica Acta, 2001, vol. 46, 3939-3941.
  37. Charging Process in Electron Conducting Polymers: Dimerization Model, M. A. Vorotyntsev, J. Heinze, Electrochimica Acta, 2001, vol. 46, 3309-3324.
  38. Time-Difference Impedance Spectroscopy of Growing Films Containing a Single Mobile Charge Carrier, with Application to Surface Films on Li Electrodes, M. A. Vorotyntsev, M. D. Levi , A. Schechter, D. Aurbach, J. Phys. Chem. B, 2001, vol. 105, 188-194.
  39. Electron and Proton Conducting Polymers: Recent Developments and Prospects, G. Inzelt, M. Pineri, J. W. Schultze, M. A. Vorotyntsev, Electrochim. Acta, 2000, vol. 45, 2403-2423.
  40. Electrochemical Impedance Spectroscopy of Thin Films with Two Mobile Charge Carriers: Effect of the Interfacial Charging, M. A. Vorotyntsev, J. P. Badiali, G. Inzelt, J. Electroanal. Chem., 1999, vol. 472, 7-19.
  41. Transport Across an Electroactive-Polymer Film in Contact with Media Allowing Both Ionic and Electronic Interfacial Exchange, M. A. Vorotyntsev, C. Deslouis, M. M. Musiani, B. Tribollet, K. Aoki, Electrochimica Acta, 1999, vol. 44, 2105-2115.
  42. Charging Process in Polypyrrole Films: Effect of Ion Association, M. A. Vorotyntsev, E. Vieil, J. Heinze, J. Electroanal. Chem., 1998, vol. 450, 121-141.
  43. Influence of Ionic Size on the Mechanism of Electrochemical Doping of Polypyrrole Films Studied by Cyclic Voltammetry, M. D. Levi, C. Lopez, E. Vieil, M. A. Vorotyntsev, Electrochimica Acta, 1997, vol. 42, 757-769.
  44. Equilibrium Properties of the System: Electrode Modified by an Electroactive Polymer Film / Electrolyte Solution, V. V. Malev, A. A. Rubashkin, M. A. Vorotyntsev, Russian Electrochemistry, 1997, vol. 33, 872-882 (945-955 in Russian).
  45. Electrokinetic Instability of Solution in a Plane-Parallel Electrochemical Cell, E. K. Zholkovskij, M. A. Vorotyntsev, E. Staude, J. Colloid and Interface Sci., 1996, vol. 181, 28-33.
  46. Potential Distribution across the Electroactive-Polymer Film between the Metal and Solution as a Function of the Film Charging Level, M. A. Vorotyntsev, A. A. Rubashkin, J. P. Badiali, Electrochimica Acta, 1996, vol. 41, 2313-2320.
  47. Ion Exchange between the Polypyrrole Film and the Lithium Perchlorate PC Solution, M. A. Vorotyntsev, E. Vieil, J. Heinze, Electrochimica Acta, 1996, vol. 41, 1913-1920.
  48. Multi-Component Diffusion Approach to the Transport across the Electroactive-Polymer Films with Two Mobile Charge Carriers, M. A. Vorotyntsev, J. P. Badiali, E. Vieil, Electrochimica Acta, 1996, vol. 41, 1375-1381.
  49. Charging-Discharging Process of Polypyrrole Films in Solutions of Tetraphenylborate Anions, M. A. Vorotyntsev, E. Vieil, J. Heinze, In: New Promising Electrochemical Systems for Rechargeable Batteries, V. Z. Barsukov and F. Beck, Eds., Kluwer Academic Publishers, Dordrecht, 1996, pp.333-346.
  50. Ionic Exchange of a Conducting-Polymer Film with the Solution during the Cyclic-Voltammetry Process, M. A. Vorotyntsev, E. Vieil, J. Heinze, Russian Electrochemistry, Memorial A N. Frumkin issue, 1995, vol.31, 1027-1035 (1112-1121 in Russian)
  51. Comparison of the AC Impedance of Conducting Polymer Films Studied as Electrode-Supported and Free-Standing Membranes, C. Deslouis, M. M. Musiani, B. Tribollet, M. A. Vorotyntsev, J. Electrochem. Society, 1995, vol.142, 1902-1908.
  52. The Membrane Properties of Electroactive Polymer Films, K. Doblhofer, M. A. Vorotyntsev, Electroactive Polymer Electrochemistry, Part 1: Fundamentals /M. E. G. Lyons, Ed., Plenum Publishing Corporation, New York, 1994, pp.375-442.
  53. On Interpretation of Optical-Beam Deflection Data at Excess of a Background Electrolyte, M. A. Vorotyntsev, C. Lopez, E. Vieil, J. Electroanal. Chem., 1994, vol. 368, 155-163.
  54. Short-Range Electron-Ion Interaction Effects in Charging the Electroactive Polymer Films, M. A. Vorotyntsev, J. P. Badiali, Electrochimica Acta, 1994, vol.39, 289-306.
  55. Modelling the Impedance Properties of Electrodes Coated with Electroactive Polymer Films, M. A. Vorotyntsev, L. I. Daikhin, M. D. Levi, J. Electroanal. Chem., 1994, vol. 364, 37-49.
  56. MONOGRAPH: Electrostatics of Media with the Spatial Dispersion, M. A. Vorotyntsev, A. A. Kornyshev, Nauka Publ., Moscow (in Russian), 1993, 240 pages.
  57. Mechanism of Cathodic Reactions at the Electron-Conducting Polymer Films: Electroreduction of Chloranyl and Tetracyanoquinodimethane at the Poly-3-Methylthiophene Coated Glassy Carbon Electrode, M. D. Levi, N. M. Alpatova, E. V. Ovsyannikova, M. A. Vorotyntsev, J. Electroanal. Chem., 1993, vol. 351, 271-284.
  58. Theory of Equilibrium and Kinetic Phenomena in Electron-Conducting Polymers, M. A. Vorotyntsev, Synthetic Metals, 1993, vol.57, 4556-4564
  59. Distribution of the Interfacial Potential Drop at Penetration of Ionic Components of the Solution into the Surface Layer of a Finite Thickness with a Fixed Spatial Charge, M. A. Vorotyntsev, Yu. A. Ermakov, V. S. Markin, A. A. Rubashkin, Russ. J. Electrochem., 1993, vol. 29, 513-525.(Elektrokhimiya, 1993, vol. 29, 596-610)
  60. Fluctuative Properties of Turbulent Mass Transfer at a Large-Scale Electrode, M. A. Vorotyntsev, E. F. Skurygin, Proceedings of the 3rd International Workshop on Electrodiffusion Diagnostics of Flows, Dourdan, France, p.149-160, 1993
  61. Isotherms of Electrochemical Doping and Cyclic Voltammograms of Electroactive Polymer Films, M. A. Vorotyntsev, L. I. Daikhin, M. D. Levi, J. Electroanal. Chem., 1992, vol. 332, 213-235.
  62. On the Analytical Properties of the Static Dielectric Function of Water, A. A. Kornyshev, D. A. Kossakowski, M. A. Vorotyntsev, In: Condensed Matter Physics Aspects of Electrochemistry / M. P. Tosi, A. A. Kornyshev, Eds., World Scientific Publ., Singapore-New Jersey-London-Hong Kong, 1991, pp. 92-109.
  63. Theory of Specific Ionic Adsorption at a Non-Transitional Metal Surface, M. A. Vorotyntsev, In: Condensed Matter Physics Aspects of Electrochemistry / M. P. Tosi, A. A. Kornyshev, Eds., World Scientific Publ., Singapore-New Jersey-London-Hong Kong, 1991, pp. 229-248.
  64. Turbulent Mass Transfer in Electrochemical Systems. Turbulence for Electrochemistry. Electrochemistry for Turbulence., M. A. Vorotyntsev, In: Condensed Matter Physics Aspects of Electrochemistry / M. P. Tosi, A. A. Kornyshev, Eds., World Scientific Publ., Singapore-New Jersey-London-Hong Kong, 1991, pp. 509-518.
  65. Diffusion-Convection Impedance at Small Electrodes, C. Deslouis, B. Tribollet, M. A. Vorotyntsev, J. Electrochem. Society, 1991, vol. 138, 2651-2657.
  66. Phenomenological Description of Dark Redox Reactions at Electrodes Coated with Conducting Polymer Films. Part II., Mechanism of Tetracyanoquinodimethane and Iodine Electroreduction at Polythiophene, M. D. Levi, M. A. Vorotyntsev, A. M. Skundin, V. E. Kazarinov, J. Electroanal. Chem., 1991, vol. 319, 243-261.
  67. Electron-Conducting Polymers: Equilibrium Characteristics and Electrode Kinetics, M. A. Vorotyntsev, M. D. Levi, In: Advances in Science & Technology. Electrochemistry / Yu. M. Polukarov, Ed., VINITI, Moscow, 1991, vol. 34, 154-220 (in Russian).
  68. Electron-Conducting Polymers: Electrochemical Doping and Equilibrium Potential Distribution across the Metal / Polymer / Solution Interface, M. D. Levi, M. A. Vorotyntsev, V. E. Kazarinov, Synthetic Metals, 1991, vol. 43, 2923-2925.
  69. Electric Field of Fractal Objects, A. A. Kornyshev, M. A. Vorotyntsev, Physica A, 1991, vol. 171, 98-119.
  70. Electric Double Layer Structure in a Surface-Inactive Electrolyte Solution: Effect of the Stern Layer and Spatial Correlations of Solvent Polarization, M. A. Vorotyntsev, P. V. Mityushev, Electrochimica Acta, 1991, vol. 36, 401-409.
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